Photo-Thermo-Mechanochemical Approach to Synthesize Quinolines via Addition/Cyclization of Sulfoxonium Ylides with 2-Vinylanilines Catalyzed by Iron(II) Phthalocyanine.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.1c04220
Abstract: A novel photo-thermo-mechanochemical approach to assembling quinolines catalyzed by iron(II) phthalocyanine has been realized for the first time. This transformation features a cost-efficient catalytic system and operational simplicity, is free of solvent, and shows good… read more here.
Keywords: photo thermo; thermo mechanochemical; mechanochemical approach; iron phthalocyanine ... See more keywords
Reductive Electrochemical Activation of Molecular Oxygen Catalyzed by an Iron-Tungstate Oxide Capsule: Reactivity Studies Consistent with Compound I Type Oxidants
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00897
Abstract: The reductive activation of molecular oxygen catalyzed by iron-based enzymes toward its use as an oxygen donor is paradigmatic for oxygen transfer reactions in nature. Mechanistic studies on these ... read more here.
Keywords: activation molecular; oxygen; catalyzed iron; oxygen catalyzed ... See more keywords
Olefin hydroboration catalyzed by an iron-borane complex.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00494e
Abstract: The well-defined iron(0) complex [(iPrDPBPh)Fe2-(μ-1,2-N2)] (A) reacts with HBpin to afford the complex [(η3-H2iPrDPB)Fe(η3-H2Bpin)] (B) via oxidative addition of the H-B bond. Complex A is an effective pre-catalyst for the hydroboration of a range of… read more here.
Keywords: olefin hydroboration; hydroboration catalyzed; iron; iron borane ... See more keywords