Effect of the substituent on C-H activation catalyzed by a non-heme Fe(IV)O complex: a computational investigation of reactivity and hydrogen tunneling.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01529c
Abstract: Density functional theory investigations were performed to address the C-H activation reactivity and the influence of quantum mechanical tunneling catalyzed by a non-heme iron(IV)-oxo complex, namely [FeIVOdpaq-X]+, where the macrocyclic ligand dpaq represents {2-[bis(pyridine-2-yl-methyl)]amino-N-quinolin-8-yl-acetamido}. Counter… read more here.
Keywords: catalyzed non; state; effect; hydrogen ... See more keywords
Manganese/bipyridine-catalyzed non-directed C(sp3)–H bromination using NBS and TMSN3
Sign Up to like & getrecommendations! Published in 2021 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.17.74
Abstract: A Mn(II)/bipyridine-catalyzed bromination reaction of unactivated aliphatic C(sp3)−H bonds has been developed using N-bromosuccinimide (NBS) as the brominating reagent. The reaction proceeded in moderate-to-good yield, even on a gram scale. The introduced bromine atom can… read more here.
Keywords: catalyzed non; non directed; bromination; bipyridine catalyzed ... See more keywords