Articles with "catalyzed ortho" as a keyword



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Ruthenium(II)-Catalyzed Ortho-C-H Alkylation of Naphthylamines with Diazo Compounds for Synthesis of 2,2-Disubstituted π-Extended 3-Oxindoles in Water.

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Published in 2020 at "Organic letters"

DOI: 10.1021/acs.orglett.0c01811

Abstract: Ruthenium(II)-catalyzed ortho-C-H alkylation of naphthylamines with diazo compounds for the synthesis of 2,2-disubstituted π-extended 3-oxindoles has been developed. The method represents the first example of C-H alkylation via carbenoid insertion in water as a sustainable… read more here.

Keywords: catalyzed ortho; naphthylamines diazo; alkylation naphthylamines; alkylation ... See more keywords
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Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives.

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Published in 2017 at "Organic letters"

DOI: 10.1021/acs.orglett.7b02936

Abstract: An iridium-catalyzed ortho-selective C-H borylation of phenol and aniline derivatives has been successfully developed. Iridium/bipyridine-catalyzed C-H borylation generally occurred at the meta- and para-positions of aromatic substrates. Introduction of an electron-withdrawing substituent on the bipyridine-type… read more here.

Keywords: catalyzed ortho; borylation; selective borylation; ortho selective ... See more keywords
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Manganese-Catalyzed ortho-C-H Amidation of Weakly Coordinating Aromatic Ketones.

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Published in 2018 at "Organic letters"

DOI: 10.1021/acs.orglett.8b01770

Abstract: An efficient manganese-catalyzed ortho-C-H amidation of weakly coordinating aromatic ketones using the readily available sulfonyl azide as the amination reagent is developed. The key step is the ketone directed aromatic metalation using the in situ… read more here.

Keywords: catalyzed ortho; coordinating aromatic; weakly coordinating; manganese catalyzed ... See more keywords
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Ruthenium-Catalyzed ortho- and meta-H/D Exchange of Arenes.

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Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b03955

Abstract: Ruthenium-catalyzed aromatic H/D exchange in [D4]acetic acid has been developed. By using N-heteroarenes as directing groups, both ortho and meta positions are selectively deuterated with high levels of D incorporation. Moreover, this strategy provides an… read more here.

Keywords: catalyzed ortho; exchange arenes; meta exchange; ortho meta ... See more keywords
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Ruthenium-catalyzed ortho-selective CAr-H amination of heteroaryl arenes with di-tert-butyldiaziridinone.

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Published in 2019 at "Chemical communications"

DOI: 10.1039/c9cc02499a

Abstract: Application of an oxidative amination reagent (di-tert-butyldiaziridinone) to the Ru3(CO)12-catalyzed ortho-selective CAr-H amination reaction is described. This strategy shows good functional group compatibility with various phenyl-substituted N-heterocycles, including biologically active substrates, thus providing synthetic potential… read more here.

Keywords: catalyzed ortho; selective car; amination; ortho selective ... See more keywords
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Theoretical Study on the Copper-Catalyzed ortho-Selective C-H Functionalization of Naphthols with α-Phenyl-α-Diazoesters

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Published in 2023 at "Molecules"

DOI: 10.3390/molecules28041767

Abstract: The aromatic C(sp2)-H functionalization of unprotected naphthols with α-phenyl-α-diazoesters under mild conditions catalyzed by CuCl and CuCl2 exhibits high efficiency and unique ortho-selectivity. In this study, the combination of density functional theory (DFT) calculations and… read more here.

Keywords: functionalization; phenyl diazoesters; catalyzed ortho; ortho selective ... See more keywords