Ruthenium-Catalyzed Peri- and Ortho-Alkynylation with Bromoalkynes via Insertion and Elimination
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DOI: 10.1021/acs.orglett.7b02655
Abstract: The alkynylation of naphthols takes place with total regiocontrol at the peri position of the hydroxyl group in the presence of [RuCl2(p-cymene)]2 as the catalyst. This reaction features high functional group tolerance. The related ortho-alkynylation… read more here.
Keywords: alkynylation; catalyzed peri; insertion; ortho alkynylation ... See more keywords