Asymmetric Induction with a Chiral Amine Catalyzed by a Ru-PNP Pincer Complex: Insight from Theoretical Investigation.
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DOI: 10.1021/acs.inorgchem.0c00823
Abstract: In this paper, the mechanism of asymmetric amination of a racemic alcohol with Ellman's sulfinamide and the origin of diastereoselectivity catalyzed by a Ru-PNP pincer complex were studied using density functional theory (DFT). The mechanism… read more here.
Keywords: pincer complex; catalyzed pnp; induction chiral; pnp pincer ... See more keywords