N‐Heterocyclic‐Carbene‐Catalyzed Reactions of Nitroalkenes: Synthesizing Important Building Blocks
Sign Up to like & getrecommendations! Published in 2018 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.201700520
Abstract: Recent developments of N-heterocyclic carbenes (NHCs)- catalyzed acyl-anion equivalent (Stetter reaction), homoenolate and enolate reactions with reactive nitroalkene as a Michael acceptor are described. Systematically, a unique strategy for NHC-catalyzed C-C bond formation reactions using… read more here.
Keywords: nitroalkenes synthesizing; catalyzed reactions; synthesizing important; reactions nitroalkenes ... See more keywords
Tunable Gold‐catalyzed Reactions of Propargyl Alcohols and Aryl Nucleophiles
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DOI: 10.1002/open.202200030
Abstract: Abstract Gold‐catalyzed transformations of 1,3‐diarylpropargyl alcohols and various aryl nucleophiles were studied. Selective tunable synthetic methods were developed for 1,1,3‐triarylallenes, diaryl‐indenes and tetraaryl‐allyl target products by C3 nucleophilic substitution and subsequent intra‐ or intermolecular hydroarylation,… read more here.
Keywords: tunable gold; diaryl indenes; aryl nucleophiles; catalyzed reactions ... See more keywords
Activation of Lipase-Catalyzed Reactions Using Ionic Liquids for Organic Synthesis.
Sign Up to like & getrecommendations! Published in 2018 at "Advances in biochemical engineering/biotechnology"
DOI: 10.1007/10_2018_62
Abstract: The use of ionic liquids to replace organic or aqueous solvents in biocatalysis processes has recently received great attention, and much progress has been made in this area; the lipase-catalyzed reactions are the most successful.… read more here.
Keywords: ionic liquids; lipase catalyzed; catalyzed reactions; organic synthesis ... See more keywords
Platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan with alkynes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.10.016
Abstract: Abstract The synthesis and platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan (1) have been reported. The reactions of 1 with diphenylacetylene and phenyl(trimethylsilyl)acetylene in the presence of a platinum catalyst gave the corresponding six-membered ring compounds produced from… read more here.
Keywords: platinum catalyzed; catalyzed reactions; reactions bis; dimethylsilyl furan ... See more keywords
Calcium-catalyzed reactions of element-H bonds
Sign Up to like & getrecommendations! Published in 2018 at "Science Bulletin"
DOI: 10.1016/j.scib.2018.06.002
Abstract: Investigation on organocalcium catalysis is just unfolding during the past decade. Beside conventional Ca salts with strong electron-withdrawing counter anions that may serve as Lewis acid catalysts, many Ca complexes have also been designed recently… read more here.
Keywords: reactions element; catalyzed reactions; element bonds; calcium catalyzed ... See more keywords
Ligand-Controlled Nickel-Catalyzed Reactions of Benzocyclobutenones with Alkynyltrifluoroborates: Diverse Construction of Polysubstituted Naphthols.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01091
Abstract: Ligand-controlled nickel-catalyzed selective cleavage of the C1-C2 or C1-C8 bond of benzocyclobutenones (BCBs) is reported. The delicate selection of dpppe or PMe3 as the ligand led to predictably divergent synthesis of a wide range of… read more here.
Keywords: controlled nickel; nickel catalyzed; catalyzed reactions; ligand ... See more keywords
Accelerated d-Fructose Acid-Catalyzed Reactions in Thin Films Formed by Charged Microdroplets Deposition.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Society for Mass Spectrometry"
DOI: 10.1021/jasms.1c00363
Abstract: Thin films derived by the deposition of charged microdroplets generated in the ESI source of a mass spectrometer act as highly concentrated reaction vessels in which the final products of an ion-molecule reaction can be… read more here.
Keywords: catalyzed reactions; fructose acid; thin films; charged microdroplets ... See more keywords
Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02405c Click here for additional data file.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Science"
DOI: 10.1039/c7sc02405c
Abstract: Several ppm level gold-catalyzed reactions enabled by the ligand HandaPhos can be performed at room temperature in aqueous nanoreactors composed of the surfactant Nok. read more here.
Keywords: catalyzed reactions; catalysis enabled; room temperature; micellar catalysis ... See more keywords
Niobium- and zirconium-catalyzed reactions of substituted 2 alkynylamines with Et2Zn
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d0ra10132j
Abstract: The NbCl5–EtMgBr-catalyzed reaction of N,N-disubstituted 2-alkynylamines with Et2Zn followed by hydrolysis or deuterolysis affords (2Z)-alkenylamines (reduction products of alkyne) in high yields. The reaction of N,N-disubstituted 2-alkynylamines with Et2Zn catalyzed by the Cp2ZrCl2–EtMgBr system occurs… read more here.
Keywords: substituted alkynylamines; zirconium catalyzed; catalyzed reactions; reactions substituted ... See more keywords
Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d1cs00966d
Abstract: Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions, where carbocations are the most common intermediates of these reaction processes, including methanol to olefins, alkene/aromatic alkylation, and hydrocarbon cracking/isomerization. The fundamental research… read more here.
Keywords: spectroscopy; chemistry; catalyzed reactions; carbocation chemistry ... See more keywords
Understanding the reaction mechanism of gold-catalyzed reactions of 2,1-benzisoxazoles with propiolates and ynamides
Sign Up to like & getrecommendations! Published in 2021 at "Organic chemistry frontiers"
DOI: 10.1039/d1qo00217a
Abstract: The detailed reaction mechanisms of gold-catalyzed reactions of 2,1-benzisoxazoles with propiolates and ynamides have been investigated with the aid of density functional theory calculations. read more here.
Keywords: catalyzed reactions; benzisoxazoles propiolates; gold catalyzed; propiolates ynamides ... See more keywords