Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.0c00044
Abstract: ConspectusThe oxygen reduction reaction (ORR) is a multiproton/multielectron transformation in which dioxygen (O2) is reduced to water or hydrogen peroxide and serves as the cathode reaction in most fuel cells. The ORR (O2 + 4e-… read more here.
Keywords: scaling relationships; porphyrin catalyzed; reaction; molecular scaling ... See more keywords
Revealing the Role of Electrostatics in Gold-Nanoparticle-Catalyzed Reduction of Charged Substrates
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DOI: 10.1021/acscatal.7b02292
Abstract: The potency of electrostatic effects arising from nanoparticle (NP) surface in Au-NP-catalyzed reduction of charged substrates are presented. The electrostatic potential around Au NPs is controlled by varying the nature of ligands and ionic strength… read more here.
Keywords: electrostatics; nanoparticle; reduction charged; catalyzed reduction ... See more keywords
Bro̷nsted Acid-Catalyzed Reduction of Furans.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c18485
Abstract: Bioderived furans play a pivotal role in advancing defossilized chemical pathways. The complete reduction of furans currently relies on impractical metal-catalyzed hydrogenations at high pressures and temperatures. In addition, the Birch reduction of unbiased furans… read more here.
Keywords: bro nsted; nsted acid; reduction; acid catalyzed ... See more keywords
9-BBN and chloride catalyzed reduction of chlorophosphines to phosphines and diphosphines.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06439h
Abstract: The commercially available Lewis acid, 9-BBN and Lewis basic [Et4N]Cl are used as catalysts for the reduction of chlorophosphines R2PCl in the presence of phenylsilane. Aryl-chlorophosphines afford primarily diphosphines (P2R4) while secondary phosphines predominate for… read more here.
Keywords: chloride catalyzed; bbn chloride; chlorophosphines phosphines; reduction chlorophosphines ... See more keywords
Pd/NHC catalyzed reduction and coupling of nitroaromatics for the synthesis of diarylamines
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DOI: 10.1039/d4ra00921e
Abstract: Herein, we report a one-pot approach to diarylamines through the reductive homocoupling of nitroaromatics, employing triethylsilane as the reducing agent and Pd/NHC as the catalyst. This method enables nitroaromatics to serve both as electrophilic reagents… read more here.
Keywords: nhc catalyzed; nitroaromatics synthesis; reduction coupling; coupling nitroaromatics ... See more keywords
(HMe2SiCH2)2: A Useful Reagent for B(C6F5)3-Catalyzed Reduction–Lactonization of Keto Acids: Concise Syntheses of (–)-cis-Whisky and (–)-cis-Cognac Lactones
Sign Up to like & getrecommendations! Published in 2017 at "Synlett"
DOI: 10.1055/s-0036-1588488
Abstract: (HMe2SiCH2)2 has been utilized as a useful reagent for B(C6F5)3-catalyzed reduction–lactonization of keto acids to synthesize γ- and δ-lactones. The process led concisely to (–)-cis-whisky and (–)-cis-cognac lactones in respective overall yields of 32% and… read more here.
Keywords: reagent c6f5; reduction lactonization; c6f5 catalyzed; lactonization keto ... See more keywords
Cobalt-Catalyzed Reduction of Aldehydes to Alcohols via the Hydroboration Reaction
Sign Up to like & getrecommendations! Published in 2024 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms25147894
Abstract: A method for the reduction of aldehydes with pinacolborane catalyzed by pincer cobalt complexes based on a triazine backbone is developed in this paper. The presented methodology allows for the transformation of several aldehydes bearing… read more here.
Keywords: reaction; reduction aldehydes; cobalt catalyzed; reduction ... See more keywords
Ir-Catalyzed Reduction of Carbonyl Compounds Using Biogenetic Alcohols
Sign Up to like & getrecommendations! Published in 2019 at "Inorganics"
DOI: 10.3390/inorganics7090114
Abstract: Biomass has gained great attention as an alternative to fuel-derived chemicals. This report concerns new catalytic systems consisting of [IrCp*Cl2]2 (Cp*: Pentamethylcyclopentadienyl) for the reduction of aldehyde and biogenetic alcohols as hydrogen sources. [IrCp*Cl2]2 has… read more here.
Keywords: reduction; reduction carbonyl; carbonyl compounds; hydrogen sources ... See more keywords