Regiodivergent metal-catalyzed B(4)- and C(1)-selenylation of o-carboranes
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DOI: 10.1039/d2sc05590b
Abstract: Regiodivergent transition metal-catalyzed B(4)- and C(1)-selenylation reactions of o-carboranes have been demonstrated. Namely, Ru(ii)-catalysis selectively generated B(4)-selenylated o-carboranes from the reaction of o-carborane acids with arylselenyl bromides with the release of carbon dioxide. In contrast,… read more here.
Keywords: metal catalyzed; selenylation; catalyzed selenylation; selenylation carboranes ... See more keywords