Stereoselective Synthesis of trans-Stilbenes through Silver-Catalyzed Self-Coupling of N-Triftosylhydrazones: An Experimental and Theoretical Study.
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DOI: 10.1021/acs.orglett.3c01040
Abstract: A silver-mediated homocoupling of N-triftosylhydrazones for the construction of trans-stilbenes has been presented. This protocol is characterized by its suitability for both inter- and intramolecular reactions, operational simplicity, high efficiency with excellent stereoselectivity, broad substrate… read more here.
Keywords: stilbenes silver; catalyzed self; trans stilbenes; stereoselective synthesis ... See more keywords
Factors Determining Selectivity of Acid- and Base-Catalyzed Self- and Cross-Condensation of Acetone and Cyclopentanone
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DOI: 10.1021/acscatal.0c02987
Abstract: In a combined kinetics and density functional theory (DFT) study, we have explored several factors that affect the selectivity of acid- and base-catalyzed self- and cross-aldol condensation of acet... read more here.
Keywords: acid base; base catalyzed; catalyzed self; self cross ... See more keywords