Copper-Catalyzed Silylation of Propargyl Carbonates: A General Entry to Allenylsilanes
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DOI: 10.1039/d3qo00371j
Abstract: A general and practical route for the silylation of propargyl car-bonates with silylboranes catalyzed by copper has been devel-oped. A wide range of propargyl carbonates with different substi-tution patterns including... read more here.
Keywords: catalyzed silylation; propargyl; silylation propargyl; propargyl carbonates ... See more keywords
Pd-Catalyzed C–H Silylation Reactions with Disilanes
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DOI: 10.1055/s-0037-1610339
Abstract: Pd-catalyzed C–H silylation reactions remain underdeveloped. General strategies usually rely on the use of complex bidentate directing groups. C,C-Palladacycles exhibit extremely high reactivity towards hexamethyldisilane and can be disilylated very efficiently. The C,C-palladacycles are prepared… read more here.
Keywords: silylation; reactions disilanes; palladacycles generated; catalyzed silylation ... See more keywords