Nickel‐Catalyzed Stereodivergent Synthesis of E‐ and Z‐Alkenes by Hydrogenation of Alkynes
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DOI: 10.1002/cssc.201900784
Abstract: Abstract A convenient protocol for stereodivergent hydrogenation of alkynes to E‐ and Z‐alkenes by using nickel catalysts was developed. Simple Ni(NO3)2⋅6 H2O as a catalyst precursor formed active nanoparticles, which were effective for the semihydrogenation of… read more here.
Keywords: hydrogenation; catalyzed stereodivergent; stereodivergent synthesis; synthesis alkenes ... See more keywords
Ligand-dependent, palladium-catalyzed stereodivergent synthesis of chiral tetrahydroquinolines
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DOI: 10.1039/d2sc02771b
Abstract: The most fundamental tasks in asymmetric synthesis are the development of fully stereodivergent strategies to access the full complement of stereoisomers of products bearing multiple stereocenters. Although great progress has been made in the past… read more here.
Keywords: catalyzed stereodivergent; dependent palladium; palladium catalyzed; synthesis ... See more keywords