Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkenyl Ethers
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DOI: 10.1021/acs.orglett.9b00946
Abstract: An improved method for the nickel-catalyzed Suzuki–Miyaura cross-coupling of alkenyl ethers is reported. This stereoconvergent protocol allows for the utilization of a wide range of alkenyl ethers and aryl boronic esters for the synthesis of… read more here.
Keywords: alkenyl ethers; catalyzed suzuki; suzuki miyaura; nickel catalyzed ... See more keywords
Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation
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DOI: 10.1021/acscatal.8b00933
Abstract: The mechanism of boron-to-nickel transmetalation, the key step of the nickel-catalyzed Suzuki-Miyaura (S-M) coupling, was examined both experimentally and theoretically. Dinuclear μ-hydroxo-bridged complexes formed by reaction of trans-[ArNi(PR3)2X] with hydroxide are not directly involved in… read more here.
Keywords: transmetalation; catalyzed suzuki; suzuki miyaura; boron nickel ... See more keywords
Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C–N bond cleavage
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DOI: 10.1039/c7ra02549a
Abstract: A palladium catalyzed Suzuki cross-coupling for construction of Csp3–Csp2 bond via Csp3–N bond activation of benzyltrimethyl-ammonium salt is described. This reaction not only offered a highly efficient approach to diarylmethanes but also paved the way… read more here.
Keywords: bond; palladium catalyzed; suzuki cross; catalyzed suzuki ... See more keywords
A regioselective C7 bromination and C7 palladium-catalyzed Suzuki–Miyaura cross-coupling arylation of 4-substituted NH-free indazoles
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DOI: 10.1039/d0ra08598g
Abstract: A regioselective C7-bromination of 4-substituted 1H-indazoles followed by a palladium-catalyzed Suzuki–Miyaura reaction with boronic acids is described. read more here.
Keywords: palladium catalyzed; suzuki miyaura; catalyzed suzuki; regioselective bromination ... See more keywords
Palladium(0) catalyzed Suzuki cross-coupling reaction of 2,5-dibromo-3-methylthiophene: selectivity, characterization, DFT studies and their biological evaluations
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DOI: 10.1186/s13065-018-0404-7
Abstract: Thiophene derivatives have shown versatile pharmacological activities. The Suzuki reaction proved a convenient method for C–C bond formations in organic molecules. In the present research work novel derivatives of 2,5-dibromo-3-methylthiophene (3a–k and 3l–p) has been… read more here.
Keywords: coupling reaction; palladium catalyzed; catalyzed suzuki; reaction ... See more keywords
Borylated norbornadiene derivatives: Synthesis and application in Pd-catalyzed Suzuki–Miyaura coupling reactions
Sign Up to like & getrecommendations! Published in 2022 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.18.41
Abstract: The photochromic norbornadiene/quadricyclane system is among the most promising candidates for molecular solar thermal (MOST) energy storage. As in this context there is still the need for new tailor-made derivatives, borylated norbornadienes were synthesized that… read more here.
Keywords: catalyzed suzuki; suzuki miyaura; borylated norbornadiene; coupling reactions ... See more keywords