Manganese catalyzed transfer hydrogenation of biomass-derived aldehydes: Insights to the catalytic performance and mechanism
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2020.05.037
Abstract: Abstract Manganese catalyzed transfer hydrogenation (CTH) of aldehydes is an attractive method for the synthesis of alcohols. Here, we report a novel and efficient MnO@C-N catalyst for the CTH of biomass-derived 5-hydroxymethylfurfural and other aldehydes… read more here.
Keywords: manganese catalyzed; transfer hydrogenation; biomass derived; transfer ... See more keywords
Ni(II)-Catalyzed Transfer Hydrogenation of Azoarenes with NH3BH3.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01529
Abstract: A nickel-catalyzed semihydrogenation of azoarenes to hydrazoarenes with NH3BH3 is developed. The catalytic system exhibits good functional group tolerance and a high turnover frequency at room temperature. Results of control and deuterium-labeling experiments indicate that… read more here.
Keywords: transfer hydrogenation; transfer; azoarenes nh3bh3; catalyzed transfer ... See more keywords
Room temperature iron catalyzed transfer hydrogenation using n-butanol and poly(methylhydrosiloxane)
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DOI: 10.1039/d0gc04175k
Abstract: Reduction of carbon–carbon double bonds is reported using a three-coordinate iron(ii) β-diketiminate pre-catalyst, PMHS and nBuOH. read more here.
Keywords: catalyzed transfer; iron catalyzed; iron; transfer hydrogenation ... See more keywords
HMPA-Catalyzed Transfer Hydrogenation of 3-Carbonyl Pyridines and Other N-Heteroarenes with Trichlorosilane
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DOI: 10.3390/molecules24030401
Abstract: A method for the HMPA (hexamethylphosphoric triamide)-catalyzed metal-free transfer hydrogenation of pyridines has been developed. The functional group tolerance of the existing reaction conditions provides easy access to various piperidines with ester or ketone groups… read more here.
Keywords: hydrogenation carbonyl; transfer hydrogenation; hmpa catalyzed; transfer ... See more keywords