Mass Spectrometric and Vibrational Characterization of Reaction Intermediates in [Ru(bpy)(tpy)(H2 O)]2+ Catalyzed Water Oxidation.
Sign Up to like & getrecommendations! Published in 2017 at "ChemPlusChem"
DOI: 10.1002/cplu.201700085
Abstract: Mass spectrometry coupled with an in-line electrochemical electrospray ionization source is used to capture some of the reaction intermediates formed in the [Ru(bpy)(tpy)(H2 O)]2+ (bpy=2,2'-bipyridine, tpy=2,2':6',2"-terpyridine) catalyzed water oxidation reaction. By controlling the applied electrochemical… read more here.
Keywords: bpy tpy; catalyzed water; reaction intermediates; oxidation ... See more keywords
Hydrophobic/Hydrophilic Directionality Affects the Mechanism of Ru-Catalyzed Water Oxidation Reaction
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c02852
Abstract: From the study of supramolecular dimers of [RuVO(pda)]+ (pda = 1,10-phenanthroline-2,9-dicarboxylic acid) and [RuVO(bda)]+ (bda = 2,2′-bipyridine-6,6′-dicarboxylate) complexes, the O–O bond-forming... read more here.
Keywords: directionality affects; affects mechanism; catalyzed water; mechanism catalyzed ... See more keywords