Sterically Hindered Tellurium(IV) Catecholate as a Lewis Acid.
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DOI: 10.1021/acs.inorgchem.2c00751
Abstract: Sterically hindered tellurium catecholate Te(Cat36)2 (Cat36 = 3,6-di-tert-butyl-catecholate) was synthesized with the reaction of amorphous Te with 3,6-di-tert-butyl-o-benzoquinone. Adducts of Te(Cat36)2 with various O- and N-donors were isolated and characterized by means of single-crystal X-ray… read more here.
Keywords: catecholate; hindered tellurium; tellurium catecholate; sterically hindered ... See more keywords
Synthesis, dynamics and redox properties of eight-coordinate zirconium catecholate complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02487b
Abstract: Reaction of the 9,9-dimethylxanthene-bis(imine)-bis(catechol) ligand XbicH4 with half an equivalent of Zr(acac)4 affords the neutral tetracatecholate complex (XbicH2)2Zr, containing four iminium ions hydrogen bonded to the catecholates. The heteroleptic bis(catecholate)-tetraphenylporphyrin complex (TPP)Zr(XbicH2) is formed from… read more here.
Keywords: xbich2; synthesis dynamics; zirconium; eight coordinate ... See more keywords
Spin transitions in ferric catecholate complexes mediated by outer-sphere counteranions.
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DOI: 10.1039/d2dt01207c
Abstract: A family of ionic ferric catecholate complexes 1-4 bearing a disubstituted 3,6-di-tert-butyl-catecholate ligand (3,6-DBCatH2) and tetradentate tris(2-pyridylmethyl)amine (TPA) was prepared and its spin transitions were investigated. Variation of the outer-sphere counteranions (PF6, BPh4, ClO4, BF4)… read more here.
Keywords: catecholate; outer sphere; sphere counteranions; spin transitions ... See more keywords
A conductive catecholate-based framework coordinated with unsaturated bismuth boosts CO2 electroreduction to formate
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DOI: 10.1039/d3sc01876h
Abstract: A conductive MOF, named Bi-based catecholate BiHHTP, exhibited excellent catalytic performance towards CO2 electroreduction. read more here.
Keywords: based framework; catecholate based; catecholate; conductive catecholate ... See more keywords