Spin transitions in ferric catecholate complexes mediated by outer-sphere counteranions.
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DOI: 10.1039/d2dt01207c
Abstract: A family of ionic ferric catecholate complexes 1-4 bearing a disubstituted 3,6-di-tert-butyl-catecholate ligand (3,6-DBCatH2) and tetradentate tris(2-pyridylmethyl)amine (TPA) was prepared and its spin transitions were investigated. Variation of the outer-sphere counteranions (PF6, BPh4, ClO4, BF4)… read more here.
Keywords: catecholate; outer sphere; sphere counteranions; spin transitions ... See more keywords