Stereoselective Construction of Chiral Linear [3]Catenanes and [2]Catenanes.
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DOI: 10.1021/jacs.2c12027
Abstract: We have successfully constructed a chiral linear [3]catenane stereoselectively by coordination-driven self-assembly using a ditopic monodentate ligand containing l-valine residues with a binuclear half-sandwich organometallic rhodium(III) unit. Furthermore, by increasing the steric hindrance of the… read more here.
Keywords: stereoselective construction; catenane; chiral linear; catenanes catenanes ... See more keywords