Cathodic Corrosion of Metal Electrodes—How to Prevent It in Electroorganic Synthesis
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Reviews"
DOI: 10.1021/acs.chemrev.1c00148
Abstract: The critical aspects of the corrosion of metal electrodes in cathodic reductions are covered. We discuss the involved mechanisms including alloying with alkali metals, cathodic etching in aqueous and aprotic media, and formation of metal… read more here.
Keywords: corrosion metal; electroorganic synthesis; metal electrodes; metal ... See more keywords
Cathodic Corrosion of a Bulk Wire to Nonaggregated Functional Nanocrystals and Nanoalloys
Sign Up to like & getrecommendations! Published in 2018 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.7b18105
Abstract: A key enabling step in leveraging the properties of nanoparticles (NPs) is to explore new, simple, controllable, and scalable nanotechnologies for their syntheses. Among “wet” methods, cathodic corrosion has been used to synthesize catalytic aggregates… read more here.
Keywords: corrosion bulk; bulk wire; corrosion; nanocrystals nanoalloys ... See more keywords
Elucidating Cathodic Corrosion Mechanisms with Operando Electrochemical Transmission Electron Microscopy.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05989
Abstract: Cathodic corrosion represents an enigmatic electrochemical process in which metallic electrodes corrode under sufficiently reducing potentials. Although discovered by Fritz Haber in the 19th century, only recently has progress been made in beginning to understand… read more here.
Keywords: electron microscopy; cathodic corrosion; microscopy; transmission electron ... See more keywords