Cathodic reductive couplings and hydrogenations of alkenes and alkynes catalyzed by the B12 model complex
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.02.002
Abstract: Abstract The reductive coupling and hydrogenation of alkenes were catalyzed by the B12 model complex, heptamethyl cobyrinate perchlorate (1), in the presence of acid during electrolysis at −0.7 V vs. Ag/AgCl in acetonitrile. Conjugated alkenes showed a… read more here.
Keywords: b12 model; catalyzed b12; model complex; electrolysis ... See more keywords
Electrochemical synthesis of 2-alkyl-4-phenylalkan-2-ols via cathodic reductive coupling of alkynes with unactivated aliphatic ketones.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06819b
Abstract: Herein, we present an efficient electrochemical method for synthesizing 2-alkyl-4-phenylalkan-2-ols through an electrochemically driven cathodic reductive coupling of the terminal and internal acetylenes with unactivated aliphatic ketones under mild conditions. The process proceeds through a… read more here.
Keywords: aliphatic ketones; reductive coupling; cathodic reductive; unactivated aliphatic ... See more keywords