Cathodic C-H Trifluoromethylation of Arenes and Heteroarenes Enabled by an in Situ-Generated Triflyltriethylammonium Complex.
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DOI: 10.1021/acs.orglett.9b02948
Abstract: While several trifluoromethylation reactions involving the electrochemical generation of CF3 radicals via anodic oxidation have been reported, the alternative cathodic, reductive radical generation has remained elusive. Herein, the first cathodic trifluoromethylation of arenes and heteroarenes… read more here.
Keywords: trifluoromethylation; triflyltriethylammonium complex; trifluoromethylation arenes; arenes heteroarenes ... See more keywords