A study of cation-dependent inverse hydrogen bonds and magnetic exchange-couplings in lanthanacarborane complexes
Sign Up to like & getrecommendations! Published in 2021 at "iScience"
DOI: 10.1016/j.isci.2021.102760
Abstract: Summary Ten lanthanacarborane complexes were synthesized to study the rare B−Hδ−∙∙∙Mn+ inverse hydrogen bonds (IHBs). The average bonding energy of B−Hδ−∙∙∙Ln3+ is theoretically determined to be larger than 24 kJ/mol, which is comparable to moderately… read more here.
Keywords: hydrogen bonds; lanthanacarborane complexes; exchange; cation dependent ... See more keywords
Cation-Dependent Electrochemistry of Polysulfides in Lithium and Magnesium Electrolyte Solutions
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DOI: 10.1021/acs.jpcc.8b06560
Abstract: In Li/S and Mg/S batteries, the charge and discharge of the sulfur cathode proceeds through a cascade of bivalent Sx2– and radical Sy•– polysulfide intermediates. The presence of Li+ or Mg2+ cations in the electrolyte… read more here.
Keywords: electrochemistry polysulfides; dependent electrochemistry; cation dependent; polysulfides lithium ... See more keywords