Synthesis and Structures of Oxygen‐Bridged Triphenylamine in Neutral, Radical Cation, and Dication States
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DOI: 10.1002/ajoc.202500264
Abstract: We have designed and synthesized a highly electron‐rich compound, an oxygen‐bridged triphenylamine incorporating methylthio groups. The radical cation and dication salts were successfully obtained by oxidation reactions of this compound as isolable solids. X‐ray crystallographic… read more here.
Keywords: cation dication; radical cation; oxygen bridged; bridged triphenylamine ... See more keywords
Stable Radical Cation and Dication of a 1,4-Disilabenzene.
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DOI: 10.1021/jacs.0c12908
Abstract: The reaction of (LSi:)2 (1; L = PhC(NtBu)2) with 2 equiv of Me3SiC2C2SiMe3 resulted in the formation of (Me3SiC2)2(Me3Si)2C4Si2(L)2 (2). 2 exhibited a one-electron transfer when treated with 1 equiv of [Ph3C]+[B(C6F5)4]- to yield [(Me3SiC2)2(Me3Si)2C4Si2(L)2]·+[B(C6F5)4]-… read more here.
Keywords: me3si 2c4si2; radical cation; me3sic2 me3si; cation dication ... See more keywords