Radical Cation Diels-Alder Reactions by TiO2 Photocatalysis.
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DOI: 10.1021/acs.orglett.9b00526
Abstract: Radical cation Diels-Alder reactions by titanium dioxide (TiO2) photocatalysis in lithium perchlorate/nitromethane solution are described. TiO2 photocatalysis promotes reactions between electron-rich dienes and dienophiles, which would otherwise be difficult to accomplish due to electronic mismatching.… read more here.
Keywords: tio2 photocatalysis; cation diels; diels alder; radical cation ... See more keywords