Cation Effect on the Electrochemical Platinum Dissolution.
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c17833
Abstract: Ensuring the stability of electrocatalysts is paramount to the success of electrochemical energy conversion devices. Degradation is a fundamental process involving the release of positively charged metal ions into the electric double layer (EDL) and… read more here.
Keywords: dissolution; cation effect; cation; effect electrochemical ... See more keywords
5-Thiaporphyrinium cation: effect of sulphur incorporation on excited state dynamics.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00522k
Abstract: We synthesised thionium-ion embedded aromatic porphyrinoids: a free-base 5-thiaporphyrinium cation and its zinc complex. The sulphur atom effectively participates in the macrocyclic π-conjugation. Fluorescence quantum yields of thiaporphyrinium cations were lower than 1% unlike oxaporphyrinium… read more here.
Keywords: thiaporphyrinium cation; excited state; sulphur; cation effect ... See more keywords