Thermodynamic Studies of Cation-Macrocycle Interactions in Nickel Pincer-Crown Ether Complexes Enable Switchable Ligation
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00431
Abstract: The thermochemistry of cation–macrocycle interactions in nickel pincer complexes bearing a hemilabile aza-15-crown-5 or aza-18-crown-6 macrocycle is investigated and applied to cation-controlled reversible ligand binding. Cation–crown interactions were examined in a noncoordinating, low polarity solvent… read more here.
Keywords: cation; interactions nickel; cation macrocycle; crown ... See more keywords