First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane anions: Synthesis, structure, properties
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121592
Abstract: Abstract The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3′-Fe(1,2-C2B9H11)2] (1) and (DBTTF)2[3,3′-Cr(1,2-C2B9H11)2] (2) were synthesized and their crystal structures were determined by single crystal X-ray diffractions. The electric… read more here.
Keywords: cation salts; dbttf c2b9h11; dibenzotetrathiafulvalene dbttf; radical cation ... See more keywords
Enantiopure and racemic radical-cation salts of B(mandelate)2- and B(2-chloromandelate)2- anions with BEDT-TTF.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00024e
Abstract: We report the first examples of radical-cation salts of BEDT-TTF with spiroborate anions [B(mandelate)2]- and [B(2-chloromandelate)2]-, synthesized from either enantiopure or racemic bidentate mandelate or chloromandelate ligands. In the salts prepared using enantiopure ligands only… read more here.
Keywords: cation salts; radical cation; mandelate chloromandelate; enantiopure racemic ... See more keywords
Dihedral-Angle Dependence of Intermolecular Transfer Integrals in BEDT-BDT-Based Radical-Cation Salts with θ-Type Molecular Arrangements
Sign Up to like & getrecommendations! Published in 2021 at "Crystals"
DOI: 10.3390/cryst11080868
Abstract: We report the structural and physical properties of a new organic Mott insulator (BEDT-BDT)AsF6 (BEDT-BDT: benzo[1,2-g:4,5-g′]bis(thieno[2,3-b][1,4dithiin). This AsF6 salt has the same structure as the PF6 salt. Although the anions are disordered, the donor molecules… read more here.
Keywords: dihedral angle; cation salts; dependence; radical cation ... See more keywords