Articles with "cation substitution" as a keyword



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Phosphorus cation substitution in TiO2 nanorods toward enhanced N2 electroreduction

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Published in 2020 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2020.146517

Abstract: Abstract Electroreduction of N2 into NH3 (NRR) under ambient conditions is an attractive alternative compared to the Haber-Bosch process. However, high activity catalyst is still desired for N2 fixation. Herein, we report for the first… read more here.

Keywords: tio2; tio2 nanorods; cation; cation substitution ... See more keywords
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Improvement in magnetic parameters of polycrystalline barium hexaferrite by nonmagnetic cation substitution and microwave processing

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Published in 2019 at "Ceramics International"

DOI: 10.1016/j.ceramint.2019.02.136

Abstract: Abstract Polycrystalline Zn Zr substituted barium hexaferrite (BaFe12-xZnx/2Zrx/2O19 where x = 0.3, 0.5, 0.7 and 1.0) specimen have been synthesized by two different methods, namely conventional and microwave sintering. The latter has resulted in magnetoplumbite phase in… read more here.

Keywords: cation substitution; cation; magnetic parameters; barium hexaferrite ... See more keywords
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Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A'BTe2O9.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00623

Abstract: Three new tellurates, namely, K2BaPb0.62Ba0.38Te2O9 (1), Rb2BaPb0.7Ba0.3Te2O9 (2), and Ba2KLiTe2O9 (3), with hexagonal triple-perovskite structures have been designed via a cation substitution strategy. All three centrosymmetric compounds crystallize in the same hexagonal space group P63/mmc.… read more here.

Keywords: cation substitution; substitution hexagonal; hexagonal triple;
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Cation Substitution and Size Effects in Ca2ZnSb2 and Yb2MnSb2: Crystal and Electronic Structures and Thermoelectric Properties.

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Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c00491

Abstract: Zintl compounds often feature complex structural fragments and small band gaps, favoring promising thermoelectric properties. In this work, a new phase Ca2ZnSb2 is synthesized and characterized to be a LiGaGe-type structure. It is isotypic to… read more here.

Keywords: substitution size; cation substitution; ca2znsb2 yb2mnsb2; thermoelectric properties ... See more keywords
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Cation Substitution Effect on a Molecular Analogue of Perovskite Manganites

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Published in 2017 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.6b11965

Abstract: A recently synthesized Mn-containing molecule Ce2IIICeIVMn8IIIO8(O2CPh)18(HO2CPh) (Ce3Mn8III) structurally resembles the repeating unit of a bulk perovskite manganite. This resemblance brings forth the intriguing possibility of studying physical properties and effects that appear in both the… read more here.

Keywords: cation substitution; effect molecular; cation; substitution effect ... See more keywords
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MOF transmetalation beyond cation substitution: defective distortion of IRMOF-9 in the spotlight

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Published in 2019 at "CrystEngComm"

DOI: 10.1039/c8ce01808a

Abstract: Zn-to-Co transmetalation of IRMOF-9 introduces major structural changes. read more here.

Keywords: cation substitution; irmof; beyond cation; mof transmetalation ... See more keywords