Molecular Origin of High Cation Transference in Mixtures of Poly(pentyl malonate) and Lithium Salt.
Sign Up to like & getrecommendations! Published in 2023 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.3c00041
Abstract: The rational development of new electrolytes for lithium batteries rests on the molecular-level understanding of ion transport. We use molecular dynamics simulations to study the differences between a recently developed promising polymer electrolyte based on… read more here.
Keywords: poly pentyl; pentyl malonate; cation; high cation ... See more keywords
Electric-Field-Induced Spatially Dynamic Heterogeneity of Solvent Motion and Cation Transference in Electrolytes.
Sign Up to like & getrecommendations! Published in 2022 at "Physical review letters"
DOI: 10.1103/physrevlett.128.198002
Abstract: While electric fields primarily result in migration of charged species in electrolytic solutions, the solutions are dynamically heterogeneous. Solvent molecules within the solvation shells of the cation will be dragged by the field while free… read more here.
Keywords: dynamic heterogeneity; heterogeneity solvent; solvent; cation ... See more keywords