LAUSR

About LAUSR
Donate
Contact Us

Follow us:

You are not signed in:

Sign Up!


   Articles with "cationic complexes" as a keyword



Photo by robertbye from unsplash

Synthesis of a new class of cationic Pd(II) complexes with 1,2,3-triazol-5-ylidene ligand and their catalytic application in the conversion of internal alkynes to 1,2-diketones

Sign Up to like & get
recommendations! Published in 2018 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2018.02.011

Abstract: Abstract A new class of cationic Pd(II) complexes of the type [Pd(Tz)(Cl)(bipy)]+Cl− and [Pd (Tz)(Cl)(phen)]+Cl− (Tz = 1,4-diaryl-3-methyl-1,2,3-triazol-5-ylidene, bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline) with various wing tip groups were synthesized from the corresponding 1,2,3-triazolium iodide via the corresponding chloro… read more here.

Keywords: new class; cationic complexes; triazol ylidene; conversion ... See more keywords
Photo by dronepilot from unsplash

Favorable Propylene-Incorporated Terpolymerization of Ethylene with CO Mediated by Cationic [P,O]-Pd and Ni Complexes.

Sign Up to like & get
recommendations! Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c03913

Abstract: Commercial polyketone materials are generally produced by palladium-catalyzed terpolymerization of ethylene and α-olefin with carbon monoxide (CO), and rare examples were reported regarding the incorporation of propylene into an ethylene/CO copolymer chain using a cost-effective… read more here.

Keywords: cationic complexes; terpolymerization; propylene; terpolymerization ethylene ... See more keywords
Photo by unstable_affliction from unsplash

The Mechanism and Kinetic Models of the Catalytic Oxidation of Ethylene by p-Benzoquinone in Aqueous–Acetonitrile Solutions of Pd(II) Cationic Complexes

Sign Up to like & get
recommendations! Published in 2018 at "Kinetics and Catalysis"

DOI: 10.1134/s0023158418040079

Abstract: A kinetic study of ethylene oxidation to acetaldehyde by p-benzoquinone in the Pd(OAc)2–HClO4−LiClO4–CH3CN–H2O system has been carried out under conditions when palladium(II) cationic complexes exist at a molar fraction of water of 0.67 and 30°С.… read more here.

Keywords: cationic complexes; mechanism kinetic; oxidation; kinetic models ... See more keywords