Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar–F Bonds
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DOI: 10.1021/jacs.2c13318
Abstract: The synthesis, isolation, and reactivity of a cationic, geometrically constrained σ3-P compound in the hexaphenyl-carbodiphosphoranyl-based pincer-type ligand (1+) are reported. 1+ reacts with electron-poor fluoroarenes via an oxidative addition-type reaction of the C–F bond to… read more here.
Keywords: metallomimetic chemistry; chemistry; geometrically constrained; catalytic hydrodefluorination ... See more keywords