Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects
Sign Up to like & getrecommendations! Published in 2019 at "Chemphyschem"
DOI: 10.1002/cphc.201900411
Abstract: Abstract Using computational approaches, we qualitatively and quantitatively assess the bonding components of a series of experimentally characterized Au(I) diarylallenylidene complexes (N.Kim, R.A.Widenhoefer, Angew. Chem. Int. Ed. 2018, 57, 4722–4726). Our results clearly demonstrate that… read more here.
Keywords: diarylallenylidene; bonding features; gold diarylallenylidene; complexes bonding ... See more keywords
Synthesis of cationic gold(III) complexes using iodine(III)
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2019.1620936
Abstract: Abstract We report the synthesis and characterization of cationic Au(III) complexes supported by nitrogen-based ligands. The syntheses are achieved by reacting Au(I) complexes [Au(N-Me-imidazole)2]+ and [Au(pyridine)(NHC)]+ with iodine(III) reagents PhI(OTf)(OAc) and [PhI(pyridine)2]2+ yielding a series… read more here.
Keywords: iii; gold iii; iii complexes; iodine iii ... See more keywords