Reactivity Studies of Cationic Au(III) Difluorides Supported by N Ligands
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DOI: 10.1021/acs.organomet.0c00429
Abstract: The reactivity of difluoro Au(III) cations supported by pyridine or imidazole ligands is reported. The Au(III)–F bond is found to be susceptible to metathesis by TMS reagents and reagents bearing a... read more here.
Keywords: cationic iii; studies cationic; iii difluorides; reactivity ... See more keywords
Rational molecular design of aggregation-induced emission cationic Ir(III) phosphors achieving supersensitive and selective detection of nitroaromatic explosives
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DOI: 10.1039/c7tc03535g
Abstract: Development of appropriate luminophores that can achieve effective sensing of nitroaromatic explosives is a crucial issue for our daily life safety and homeland security. Herein, supersensitive and highly selective detection of one nitroaromatic explosive, i.e.… read more here.
Keywords: detection; cationic iii; aggregation induced; selective detection ... See more keywords
New cationic Ir(III) complexes without “any soft substituents”: aggregation-induced emission and piezochromic luminescence
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DOI: 10.1039/c8tc04512g
Abstract: Two new aggregation-induced emission (AIE)-active cationic Ir(III) complexes with relatively rigid ligands have been rationally designed and synthesized, exhibiting excellent piezochromic luminescence (PCL) properties. In the solid state, their emission colours are tunable by a… read more here.
Keywords: cationic iii; induced emission; iii complexes; aggregation induced ... See more keywords
A mechanochromic cyclemetalated cationic Ir(III) complex with AIE activity by strategic modification of ligands.
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DOI: 10.1039/d0dt02526g
Abstract: Two new aggregation-induced emission (AIE)-active cyclemetalated cationic Ir(iii) complexes have been rationally designed and synthesized by introducing O-H substituents into Schiff base ligands. π-Hydrogen bonding is successfully exploited for the first time to realize the… read more here.
Keywords: cationic iii; mechanochromic cyclemetalated; aie; hydrogen bonding ... See more keywords
AIPE-active cationic Ir(III) complexes for efficient detection of 2,4,6-trinitrophenol and oxygen.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03537e
Abstract: A cationic Ir(III) complex, Ir2, with a diphenylamino (DPA)-substituted 2-phenylbenzothiazole derivative as the cyclometalating ligand was designed and synthesized. Ir2 shows obvious aggregation-induced phosphorescent emission (AIPE) in H2O/CH3CN, compared with a non-DPA-substituted Ir1. The AIPE-active… read more here.
Keywords: aipe active; efficient detection; detection trinitrophenol; detection ... See more keywords