A novel 3D AgI cationic metal–organic framework based on 1,2,4,5-tetra(4-pyridyl) benzene with selective adsorption of CO2 over CH4, H2O over C2H5OH, and trapping Cr2O72–
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.05.070
Abstract: Abstract A novel 3D cationic metal–organic framework, {[AgTPB]∙SbF6}n (namely 1), based on AgI and 1,2,4,5-tetra(4-pyridyl) benzene (TPB) was successfully generated under the diffusion synthesis method. The as-synthesized crystal has been investigated and characterized by physicochemical… read more here.
Keywords: metal organic; organic framework; pyridyl benzene; cationic metal ... See more keywords
Two-Fold Interlocking Cationic Metal-Organic Framework Material with Exchangeable Chloride for Perrhenate/Pertechnetate Sorption.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01846
Abstract: Albeit reported substantial sorbents for elimination of TcO4-, the issue of secondary contamination caused by released counterions (such as NO3-) from the cationic metal-organic framework (MOF) has not come into the sufficient limelight for researchers.… read more here.
Keywords: organic framework; sorption; cationic metal; metal organic ... See more keywords
Triazole-Based Cu(I) Cationic Metal-Organic Frameworks with Lewis Basic Pyridine Sites for Selective Detection of Ce3+ Ions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02215
Abstract: A highly symmetric bis-triazole-pyridine-based organic ligand, i.e., 3,5-di(4H-1,2,4-triazol-4-yl)pyridine (L), and Cu(II) salts were used to synthesize three cationic Cu(I) metal-organic frameworks (MOFs), namely, {[Cu(L)]·(NO3)·(H2O)}n (1), {[Cu(L)]·(BF4)·0.5H2O}n (2), and {[Cu1.25(L)]·1.25(ClO4)·H2O}n (3). All three MOFs have nonbonded… read more here.
Keywords: cationic metal; organic frameworks; pyridine; metal organic ... See more keywords
Effectively Decontaminating Protein-Bound Uremic Toxins in Human Serum Albumin Using Cationic Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c15864
Abstract: In the field of replacement of conventional dialysis treatment, searching superior materials for removal of protein-bound uremic toxins is a challenge on account of strong interactions between proteins and uremic toxins. Herein, we first adopted… read more here.
Keywords: protein bound; cationic metal; organic frameworks; metal organic ... See more keywords