Cationic palladium(II)–acetylacetonate complexes containing phosphine and aminophosphine ligands and their catalytic activities in telomerization of 1,3-butadiene with methanol
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121413
Abstract: Abstract The Pd(II) complexes [Pd(acac)(L)n]BF4 were synthesized by the reaction of [Pd(acac)(MeCN)2]BF4 with L (n = 2: L = PCyPh2, PCy2Ph, P(NMe2)3, P(NEt2)3, tri-2-furylphosphine, tri-2-thienylphosphine; n = 1: L = 2 dicyclohexylphosphino-2′,6′-dimethoxybiphenyl, 2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl). The structural features of the complexes were analyzed by NMR… read more here.
Keywords: palladium; cationic palladium; bf4; telomerization butadiene ... See more keywords
Cationic palladium(ii)-catalyzed synthesis of substituted pyridines from α,β-unsaturated oxime ethers
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DOI: 10.1039/d2ra03875g
Abstract: An efficient method for the synthesis of multi-substituted pyridines from β-aryl-substituted α,β-unsaturated oxime ethers and alkenes via Pd-catalyzed C–H activation has been developed. The method, using Pd(OAc)2 and a sterically hindered pyridine ligand, provides access… read more here.
Keywords: substituted pyridines; palladium catalyzed; synthesis; oxime ethers ... See more keywords
Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28104141
Abstract: The Pd(II) complexes [Pd(Cp)(L)n]m[BF4]m were synthesized via the reaction of cationic acetylacetonate complexes with cyclopentadiene in the presence of BF3∙OEt2 (n = 2, m = 1: L = PPh3 (1), P(p-Tol)3, tris(ortho-methoxyphenyl)phosphine (TOMPP), tri-2-furylphosphine, tri-2-thienylphosphine;… read more here.
Keywords: phosphine; novel route; palladium cyclopentadienyl; route cationic ... See more keywords