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Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c7qo00290d
Abstract: We introduce Li+ involving cycloadditions between acetylene and ring-like cycloparaphenylenes (CPPs) in theory. Orbital analysis suggests an inverse electron-demand mechanism in which the diene CPP acts as an electron acceptor. Partial electron transfer to Li+…
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Keywords:
diels alder;
cationic prompted;
study cationic;
mechanistic study ... See more keywords