Articles with "cationic silyne" as a keyword



Base-Stabilized Cationic Silyne with a π-Accepting Phosphonio Substituent.

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Published in 2023 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.3c00513

Abstract: A base-stabilized C-phosphonio-Si-amino-silyne 3 was synthesized, using an original method, through a coupling reaction between two Lewis-base-stabilized low-valent species: a silyliumylidene ion 1 and a P,S-bis-ylide 2 [C(0)-complex]. This new isolable cationic silyne 3 displays… read more here.

Keywords: base stabilized; phosphonio substituent; silyne; stabilized cationic ... See more keywords