Planar pentacoordinate carbon in a sulphur-surrounded boron wheel: the global minimum of CB5S5.
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DOI: 10.1039/d1cc07313c
Abstract: We report a σ + π double aromatic CB5S5+ cluster, the first global minimum unusually having a planar hypercoordinate carbon inside a boron wheel. Five peripheral sulfur atoms stabilize the carbon-centered boron wheel by weakening… read more here.
Keywords: carbon; cb5s5; global minimum; boron ... See more keywords