Tri- and pentanuclear CuII–CdII complexes of N2O2 donor ligands with the variation of carboxylate coligands: Structural elucidation and theoretical study
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120351
Abstract: Abstract Three new heterometallic copper(II)-cadmium(II) complexes [(CuL1)2Cd3(C6H5CO2)6] (1), {[(CuL2)2Cd(o-(NO2)C6H4CO2)2]·2NCMe} (2), and [{CuL2(H2O)0.65(NCMe)0.35}2Cd3(m-(NO2)C6H4CO2)6] (3) have been synthesized using [CuL1]/[CuL2] as metalloligand (where H2L1 = N,N′-bis(2-hydroxynaphthyl-methylidene)-1,3-propanediamine, H2L2 = N,Ń-bis(methyl2-hydroxynaphthyl-methylidene)-1,3-propanediamine). Single crystal structure analyses reveal that complexes 1… read more here.
Keywords: cuii cdii; pentanuclear cuii; cdii; tri pentanuclear ... See more keywords
Removal of EDTA-chelated CdII by sulfidated nanoscale zero-valent iron: Removal mechanisms and influencing factors
Sign Up to like & getrecommendations! Published in 2021 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2021.119332
Abstract: Abstract In this study, the removal mechanisms of sulfidated nanoscale zero-valent iron (S-nZVI) toward EDTA-chelated CdII (CdII-EDTA) and the detailed effects of some critical factors on CdII-EDTA removal by S-nZVI were systematically investigated. The results… read more here.
Keywords: removal mechanisms; cdii; sulfidated nanoscale; cdii edta ... See more keywords
Transmetalation for Flexible Pendant-Armed Schiff-Base Macrocyclic Complexes Influenced by Halide Effects.
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DOI: 10.1021/acs.inorgchem.7b02835
Abstract: Three 46-membered [2 + 2] pendant-armed Schiff-base macrocyclic dinuclear CdII and CuII complexes (2a, 2b, and 3b) and one 23-membered [1 + 1] CuII macrocycle 4a were prepared from the template-directed condensation reactions between 1,2-bis(2-aminoethoxy)-ethane… read more here.
Keywords: transmetalation; znii; macrocyclic complexes; cdii ... See more keywords
CdII/ZnII discrimination using 2,5-diphenyl[1,3,4]oxadiazole based fluorescent chemosensors
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj00113h
Abstract: The coordination properties and photochemical response of two fluorescent ligands 2,5-bis{2-[bis(2-pyridylmethyl)aminomethyl]phenyl}[1,3,4]oxadiazole (L1) and 2,5-bis{2-[(1,4,7-triazacyclononane-1-yl)methyl]phenyl}[1,3,4]oxadiazole (L2) towards ZnII and CdII are reported. The ligands contain the 2,5-diphenyl[1,3,4]oxadiazole (PPD) fluorescent probe linked to two coordinating units, namely… read more here.
Keywords: znii discrimination; cdii znii; cdii; diphenyl oxadiazole ... See more keywords