Bottom-up synthesis of functionalized {Ce4(SiW9O34)2(L)2} polyoxometalates
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DOI: 10.1039/c8ce01447g
Abstract: The reaction of Na10[SiW9O34] with the 4f tetravalent cerium cation associated with four different organic O/N-donor ligands at pH = 4–4.5 gives rise to the formation of five anionic polyoxometalates [Ce4(μ3-O)2(SiW9O34)2(C4H5O4)2]10− (1), [Ce4(μ3-O)2(SiW9O34)2(C5H7O4)2]10− (2), [Ce4(μ3-O)2(SiW9O34)2(C5H8O2–NH3)2]8−… read more here.
Keywords: functionalized ce4; synthesis functionalized; bottom synthesis; ce4 siw9o34 ... See more keywords