Tridentate Ligand with Three Carbanions as Donor Atoms: Formation of Dinuclear, Heptacyclic Complexes of Boron, Aluminum, or Gallium with B-C-B, Al-C-Al, or Ga-C-Ga Three-Center-Two-Electron Bonds.
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DOI: 10.1021/acs.inorgchem.0c00254
Abstract: The trilithium compound 1,3-[PhMe2Si-C(Li)═C(H)]2C6H3Li (2b) reacted with BCl3, AlCl3, or GaCl3 by salt elimination to yield dinuclear heptacyclic compounds (4). Two tridentate tricarbanionic ligands coordinate two B, Al, or Ga atoms and adopt a helical… read more here.
Keywords: three center; electron bonds; center two; chemistry ... See more keywords
High-Pressure Bonding Mechanism of Selenium Nitrides.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02889
Abstract: The high-pressure phase diagrams of binary Se-N system have been constructed using the CALYPSO method and first-principles calculations. Four stable compounds ( Cmc21-SeN2, P21 /m-SeN3, P1̅-SeN4, and P1̅-SeN5) were identified at high pressures. Various peculiar… read more here.
Keywords: nitrogen; mechanism; center two; high pressure ... See more keywords