Specific Cα-C Bond Cleavage of β-Carbon-Centered Radical Peptides Produced by Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry
Sign Up to like & getrecommendations! Published in 2018 at "Journal of The American Society for Mass Spectrometry"
DOI: 10.1007/s13361-018-1958-2
Abstract: AbstractRadical-driven dissociation (RDD) of hydrogen-deficient peptide ions [M − H + H]·+ has been examined using matrix-assisted laser dissociation/ionization in-source decay mass spectrometry (MALDI-ISD MS) with the hydrogen-abstracting matrices 4-nitro-1-naphthol (4,1-NNL) and 5-nitrosalicylic acid (5-NSA). The preferential fragment ions… read more here.
Keywords: carbon centered; centered radical; mass spectrometry;
Stepwise Bi-Bi Bond Formation: From a Bi-centered Radical to Bi4 Butterfly and Bi8 Cuneane-Type Clusters.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01657
Abstract: In contrast to their lighter homologues (P, As, Sb), the synthesis of polybismuthane clusters is still restricted to classical solid-state approaches. We herein report on systematic reduction reactions of different bismuth precursors with Ga(I) and… read more here.
Keywords: bi4; centered radical; formation; stepwise bond ... See more keywords
Carbon-centered Radical Based Dynamic Covalent Chemistry for Stimuli-responsive Chromic Materials
Sign Up to like & getrecommendations! Published in 2023 at "Journal of Materials Chemistry C"
DOI: 10.1039/d3tc00117b
Abstract: As one of the essential smart materials, stimuli-responsive chromic materials have received increasing research attention because of their visualization effects induced by external stimuli, including temperature, light, and mechanical stress.... read more here.
Keywords: chromic materials; responsive chromic; stimuli responsive; chemistry ... See more keywords