Cerium-Catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation.
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DOI: 10.1021/jacs.8b08781
Abstract: We describe a synergistic utilization of cerium photocatalysis and photoinduced electron transfer catalysis that enables an atom- and step-economical ring expansion of readily available cycloalkanols. This operationally simple protocol provides rapid access to privileged and… read more here.
Keywords: cycloaddition cycloalkanols; cerium; formal cycloaddition; cerium catalyzed ... See more keywords