Oxovanadium(IV), cerium(III), thorium(IV) and dioxouranium(VI) complexes of 1-ethyl-4-hydroxy-3-(nitroacetyl)quinolin-2(1H)-one: Synthesis, spectral, thermal, fluorescence, DFT calculations, antimicrobial and antitumor studies
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.11.081
Abstract: Abstract A new series of mononuclear oxovanadium(IV), cerium(III), thorium(IV) and dioxouranium(VI) complexes of a quinolinone ligand; 1-ethyl-4-hydroxy-3-(nitroacetyl)quinolin-2(1H)-one (H 2 L) have been synthesized. The metal complexes were characterized by different techniques such as elemental and… read more here.
Keywords: oxovanadium cerium; thorium dioxouranium; thorium; antitumor ... See more keywords
Synthesis and structural characterization of dinuclear cerium(III) and erbium(III) complexes of nicotinic acid or 2-aminobenzoic acid
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.05.057
Abstract: Abstract A cerium(III) complex, [Ce2(NA)6(H2O)4] (1) and an erbium(III) complex, [Er2(2-AMB)6(H2O)4]·3H2O (2), where NA = nicotinic acid and 2-AMB = 2-aminobenzoic acid, have been prepared and characterized by IR spectroscopy, thermogravimetric analysis and X-ray crystallography. The single crystal analysis… read more here.
Keywords: iii; oxygen; geometry; cerium iii ... See more keywords
Insights into the Spin Dynamics of Mononuclear Cerium(III) Single-Molecule Magnets
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DOI: 10.1021/acs.inorgchem.2c00958
Abstract: Four novel CeIII mononuclear complexes of formulas [Ce(ntfa)3(MeOH)2] (1), [Ce(ntfa)3(5,5′-Me2bipy)] (2), [Ce(ntfa)3(terpy)] (3), and [Ce(ntfa)3(bipy)2] (4), where ntfa = 4,4,4-trifluoro-1-(naphthalen-2-yl)butane-1,3-dionato, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-dipyridyl, terpy = 2,2′:6′,2″-terpyridine, and bipy = 2,2′-bipyridine, have been synthesized and structurally… read more here.
Keywords: mononuclear cerium; dynamics mononuclear; cerium iii; iii single ... See more keywords
Cerium(III) Carbonate Formation from {CeCp*2H}2 and Carbon Dioxide: Structure and Mechanistic Insights
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DOI: 10.1021/acs.organomet.7b00639
Abstract: The reaction between {CeCp*2H}2 with CO2 in thf resulted in a new cerium(III) carbonate species, {Ce(Cp*)2(thf)}2(μ-η2:η1-CO3). Investigations into the mechanism suggest the intermediacy of a bridging oxo-complex, {CeCp*2(thf)x}2(μ-O), which could either be formed from the… read more here.
Keywords: cecp; iii carbonate; cerium iii;
Smart, Biomimetic Periosteum Created from the Cerium(III, IV) Oxide-Mineralized Eggshell Membrane.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c02079
Abstract: The periosteum orchestrates the microenvironment of bone regeneration, including facilitating local neuro-vascularization and regulating immune responses. To mimic the role of natural periosteum for bone repair enhancement, we adopted the principle of biomimetic mineralization to… read more here.
Keywords: biomimetic periosteum; cerium iii; periosteum; cerium ... See more keywords
Isolation of heterometallic cerium(iii) complexes with a multidentate nitrogen-phosphorus ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04555d
Abstract: Heterometallic complexes play an important role in catalysis and activation of small molecules due to the synergistic effects from different metals. Here we report a straightforward strategy to construct a series of heterobimetallic complexes of… read more here.
Keywords: phosphorus ligand; nitrogen phosphorus; multidentate nitrogen; cerium iii ... See more keywords
Atomic/molecular layer deposition of cerium(III) hybrid thin films using rigid organic precursors.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00353h
Abstract: An atomic/molecular layer deposition (ALD/MLD) process for the fabrication of cerium-based metal-organic hybrid films is demonstrated for the first time. The highly reactive cerium(III) guanidinate precursor [Ce(dpdmg)3] was employed in combination with organic precursors composed… read more here.
Keywords: layer deposition; atomic molecular; cerium iii; molecular layer ... See more keywords
Kinetics analysis of the forward extraction of cerium(III) by D2EHPA from chloride medium in the presence of two complexing agents using a constant interfacial area cell with laminar flow
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DOI: 10.1515/gps-2017-0035
Abstract: Abstract The kinetic studies performed on the forward extract of cerium(III) from chloride solution with the complex agents, citric acid (H3Cit) and lactic acid (HLac) in the presence of di-(2-ethylhexyl)phosphoric acid (D2EHPA, H2A2) have been… read more here.
Keywords: extraction; using constant; interfacial area; rate ... See more keywords