Cerium-mediated photooxidation for tuning pH-dependent oxidase-like activity
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.125471
Abstract: Abstract Industrial and medical applications of most nanozymes are often limited by their pH-dependent activities as well as by weak response to external stimuli. Here we report a light-controlled nanozyme possessing tunable oxidase-like activities without… read more here.
Keywords: oxidase like; oxidase; photooxidation tuning; tuning dependent ... See more keywords
Photoinduced ligand to metal charge transfer enabling cerium mediated decarboxylative alkylation of quinoxalin-2(1H)-ones.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00840h
Abstract: Here, we report the cerium-mediated decarboxylative alkylation of quinoxalin-2(1H)-ones utilizing feedstock carboxylic acids as a radical precursor via photoinduced-LMCT. This operationally simple protocol overcomes the limitation of the direct use of carboxylic acids to access… read more here.
Keywords: cerium mediated; alkylation quinoxalin; decarboxylative alkylation; quinoxalin ones ... See more keywords