Reaction of CF3-ynones with methyl thioglycolate. Regioselective synthesis of 3-CF3-thiophene derivatives
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2018.07.013
Abstract: Abstract Efficient regioselective synthesis of 3-CF3-substituted thiophene derivatives was elaborated using addition of methyl thioglycolate to CF3-ynones in the presence of sodium methoxide. read more here.
Keywords: cf3 ynones; cf3; synthesis cf3; thiophene derivatives ... See more keywords
Synthesis of functionalized quinolines from the cascade reactions of N-aryl amidines with two CF3-ynones via C−H/N−H/C−N/C−C bond cleavage
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DOI: 10.1039/d3qo02070c
Abstract: Presented herein is a novel synthesis of CF3- and alkynyl-substituted quinoline derivatives based on Rh(III)-catalyzed cascade reactions of N-aryl amidines with two CF3-ynones. The formation of products involves a cascade... read more here.
Keywords: aryl amidines; reactions aryl; two cf3; cascade reactions ... See more keywords
Acid-Switchable Synthesis of Trifluoromethylated Triazoles and Isoxazoles via Reaction of CF3-Ynones with NaN3: DFT Study of the Reaction Mechanism
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DOI: 10.3390/ijms232314522
Abstract: A detailed study of the reaction of CF3-ynones with NaN3 was performed. It was found that the reaction permits the selective synthesis of either 4-trifluoroacetyltriazoles or 5-CF3-isoxazoles. The chemoselectivity of the reaction was switchable via… read more here.
Keywords: reaction; cf3 ynones; ynones nan3; reaction cf3 ... See more keywords