Photoinduced Trifluoromethylation with CF3Br as a Trifluoromethyl Source: Synthesis of α-CF3-Substituted Ketones
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DOI: 10.1021/acsomega.2c01241
Abstract: An efficient and novel photoinduced trifluoromethylation employing CF3Br as a trifluoromethyl source is described. With commercially accessible fac-Ir(III)(ppy)3 as the catalyst, radical trifluoromethylation between O-silyl enol ether and CF3Br occurs successfully. This method provides various… read more here.
Keywords: substituted ketones; trifluoromethyl source; cf3 substituted; cf3br trifluoromethyl ... See more keywords