Alkyne-alkenyl coupling at a diruthenium complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02866b
Abstract: Dimetallic complexes are suitable platforms for the assembly of small molecular units, and the reactivity of bridging alkenyl ligands has been widely investigated to model C-C bond forming processes. Here, we report the unusual coupling… read more here.
Keywords: alkyne alkenyl; diruthenium; cf3so3 cf3so3; alkenyl coupling ... See more keywords
A Comprehensive Analysis of the Metal–Nitrile Bonding in an Organo-Diiron System
Sign Up to like & getrecommendations! Published in 2021 at "Molecules"
DOI: 10.3390/molecules26237088
Abstract: Nitriles (N≡CR) are ubiquitous in coordination chemistry, yet literature studies on metal–nitrile bonding based on a multi-technique approach are rare. We selected an easily-available di-organoiron framework, containing both π-acceptor (CO, aminocarbyne) and donor (Cp =… read more here.
Keywords: analysis; system; metal nitrile; nitrile bonding ... See more keywords