Articles with "ch2" as a keyword



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A quantum chemical study on the formation of ethanimine (CH3CHNH) in the interstellar ice

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Published in 2018 at "Astrophysics and Space Science"

DOI: 10.1007/s10509-018-3399-6

Abstract: Ethanimine (CH3CHNH) is an important prebiotic molecule since it is a precursor of amino acid α$\alpha $-alanine in Strecker synthesis. Two isomers (E and Z) of ethanimine were detected in the molecular cloud Sagittarius B2… read more here.

Keywords: formation ethanimine; ethanimine; ch2; formation ... See more keywords
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Study on the effect of linear alkyl [CH2CH2]m and ether [CH2CH2O]m groups in the α,ω-hydroxy telechelic poly(L-lactide) (HOPLLAOH) and their poly(ester-urethanes) (PEUs). Synthesis and Characterization

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Published in 2017 at "Journal of Polymer Research"

DOI: 10.1007/s10965-017-1364-7

Abstract: Abstractα,ω-Hydroxy telechelic poly(L-lactides) (HOPLLAOH) were synthesized by ring-opening polymerization of the L-lactide (L-LA) catalyzed by tin octoate [Sn(Oct)2] in the presence of two different types of initiators such as alkyl diols [HO−(CH2−CH2)m−OH] and ether diols… read more here.

Keywords: hydroxy telechelic; ch2; poly; effect ... See more keywords
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Synthesis, physicochemical and biological evaluation of tacrine derivative labeled with technetium-99m and gallium-68 as a prospective diagnostic tool for early diagnosis of Alzheimer's disease.

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Published in 2019 at "Bioorganic chemistry"

DOI: 10.1016/j.bioorg.2019.103136

Abstract: Design, physicochemical and biological studies of novel radioconjugates for the early diagnosis of Alzheimer's disease, based on the newly synthesized tacrine derivatives were performed. Novel tacrine analogues were labeled with technetium-99m and gallium-68. For all… read more here.

Keywords: ch2; alzheimer disease; ch2 9tacrine; early diagnosis ... See more keywords
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Functionalization of CeO2-SiO2-(CH2)3-Cl nanoparticles with sodium alginate for enhanced and effective CdII, PbII, and ZnII ions removal by microwave irradiation and adsorption technique

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Published in 2020 at "Environmental Nanotechnology, Monitoring and Management"

DOI: 10.1016/j.enmm.2020.100367

Abstract: Abstract A novel nanocomposite cored of cerium oxide nanoparticles (CeO2) linked with sodium alginate (Sod. Alg) using 3-chloroopropyltrimethoxysilane was synthesized via a green synthesis method using microwave irradiation to yield a new (CeO2-Si-(CH2)3-Alg) nanocomposite. Its… read more here.

Keywords: ch2; znii ions; pbii; irradiation ... See more keywords
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The coordination chemistry of sulfonyl-substituted thioureas towards the d8 metal centres platinum(II), palladium(II), nickel(II) and gold(III)

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Published in 2021 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2021.120506

Abstract: Abstract Reactions of the complexes cis-[PtCl2(PPh3)2], [PtCl2(dppp)] (dppp = Ph2P(CH2)3PPh2), [MCl2(dppe)] (dppe = Ph2P(CH2)2PPh2, M = Ni, Pd), [PdCl2(bipy)] (bipy = 2,2′-bipyridine) and [AuCl2(bp)] (bp = cyclometallated 2-benzylpyridine) with p-TolSO2NHC(S)NHPh and Et3N in refluxing methanol gave a series of new thiourea complexes containing the ligand… read more here.

Keywords: ch2; coordination chemistry; nph pph3; chemistry ... See more keywords

Synthesis, structure, lattice energy and enthalpy of 2D hybrid perovskite [NH3(CH2)4NH3]CoCl4, compared to [NH3(CH2)nNH3]CoCl4, n=3–9

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Published in 2017 at "Journal of Crystal Growth"

DOI: 10.1016/j.jcrysgro.2016.08.006

Abstract: Abstract A new organic–inorganic 2D hybrid perovskite [NH3(CH2)4NH3]CoCl4,1,4butane diammonium tetra-chlorocobaltate, has been synthesized. Blue prismatic single crystals were grown from ethanolic solution in 1:1 stoichiometric ratio (organic/inorganic) by gradual cooling to room temperature after heating at… read more here.

Keywords: ch2 4nh3; ch2; cocl4; nh3 ch2 ... See more keywords
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Dinuclear organotin compounds carrying naphthylene- and biphenylene-spacer groups

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Published in 2020 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2020.121344

Abstract: Abstract The reaction of XMg−CH2−Y−CH2−MgX [Y = 2,6−naphthylene (−C10H6−) or 1,1’−biphenylene (−C12H8−); X = Cl or Br] with two molar equivalents of Ph3SnCl or Ph2(Me3SiCH2)SnI gave Ph3Sn−CH2−C10H6−CH2−SnPh3 (1), Ph3Sn−CH2−C12H8−CH2−SnPh3 (2) and Ph2(Me3SiCH2)Sn−CH2−C12H8−CH2−Sn(CH2SiMe3)Ph2 (3), respectively, in good yields. Reaction of… read more here.

Keywords: ch2; c12h8 ch2; dinuclear organotin; compounds carrying ... See more keywords
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Synthesis and characterization of Fe3O4@SiO2@(CH2)3NH(CH2)2O2P(OH)2 and its catalytic application in the synthesis of benzo-[h]quinoline-4-carboxylic acids via a cooperative anomeric based oxidation mechanism

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Published in 2020 at "Molecular Catalysis"

DOI: 10.1016/j.mcat.2020.110924

Abstract: Abstract In this study, Fe3O4@SiO2@(CH2)3NH(CH2)2O2P(OH)2 as a new and recoverable nanocatalyst with magnetic properties was synthesized. The characterization of the novel nanocatalyst confirmed by thermo gravimetric analysis/ differential thermal analysis (TGA/DTA), transmission electron microscopy (TEM),… read more here.

Keywords: microscopy; ch2; sio2 ch2; fe3o4 sio2 ... See more keywords
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Cyanine Masking: A Strategy to Test Functional Group Effects on Antibody Conjugate Targeting.

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Published in 2022 at "Bioconjugate chemistry"

DOI: 10.1021/acs.bioconjchem.2c00083

Abstract: Conjugates of small molecules and antibodies are broadly employed diagnostic and therapeutic agents. Appending a small molecule to an antibody often significantly impacts the properties of the resulting conjugate. Here, we detail a systematic study… read more here.

Keywords: strategy test; strategy; ch2; test functional ... See more keywords
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Mechanisms of Formaldehyde and C2 Formation from Methylene Reacting with CO2 Adsorbed on Ni(110)

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Published in 2018 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.8b00945

Abstract: Methylene (CH2) is thought to play a significant role as a reaction intermediate in the catalysis of methane dry reforming as well as in converting synthesis gas to light olefins via Fischer–Tropsch synthesis. Here, we… read more here.

Keywords: co2 adsorbed; mechanisms formaldehyde; ch2; formation ... See more keywords
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Synthesis and Solid-State Properties of PolyC3 (Co)polymers Containing (CH2–CH2–C(COOR)2) Repeat Units with Densely Packed Fluorocarbon Lateral Chains

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Published in 2019 at "Macromolecules"

DOI: 10.1021/acs.macromol.9b01559

Abstract: The synthesis and structural characterization of linear PolyC3 polymers containing trimethylene-1,1-dicarboxylate structural repeat units with C6F13 and C8F17 fluorinated side chains is described for the first time, and their properties were compared with the traditional… read more here.

Keywords: polymers containing; solid state; polyc3 polymers; ch2 ... See more keywords