Interactions of Verkade's Superbase with Strong Lewis Acids: From Labile Mono- and Binuclear Lewis Acid-Base Complexes to Phosphenium Cations.
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DOI: 10.1021/acs.inorgchem.7b01719
Abstract: A series of mono- and binuclear Lewis acid-base complexes of the formulas N[CH2CH2N(Pri)]3P→LA [LA = BH3 (8), Ga(C6F5)3 (10), GaCl3 (11)], LA←N[CH2CH2N(Pri)]3P [LA = Al(C6F5)3 (6a), AlMe3 (6b), AlEt3 (6c), AlBui3 (6d), BF3 (13)], and… read more here.
Keywords: lewis acid; pri; ch2ch2n pri; base ... See more keywords