Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization, and Catalytic Studies.
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DOI: 10.1021/acs.inorgchem.1c02749
Abstract: We report on the synthesis and structural characterization of a giant, discrete, and neutral molecular disk, [Pd40O24(OH)16{(CH3)2AsO2}16] (Pd40), comprising a 40-palladium-oxo core that is capped by 16 dimethylarsinate moieties, resulting in a palladium-oxo cluster (POC)… read more here.
Keywords: disk pd40o24; synthesis structural; ch3 2aso2; molecular disk ... See more keywords
Mixed-valent palladium(IV/II)-oxoanion, [PdIVO6PdII6((CH3)2AsO2)6]2.
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DOI: 10.1039/d2cc05699b
Abstract: We report on the first example of a PdIV-containing polyoxopalladate(II). The discrete mixed-valent polyoxopalladate(IV/II), [PdIVPdII6O6((CH3)2AsO2)6]2-, comprising a central PdIV ion that is surrounded by a six-membered PdII-oxo ring capped by six dimethylarsinate groups, was synthesized… read more here.
Keywords: palladium oxoanion; valent palladium; oxoanion pdivo6pdii6; mixed valent ... See more keywords
Mixed noble metal-oxo clusters: platinum(IV)-gold(III) oxoanion [PtIV2AuIII3O6((CH3)2AsO2)6].
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00243h
Abstract: The first discrete mixed platinum(IV)-gold(III) oxoanion [PtIV2AuIII3O6((CH3)2AsO2)6]- (1) was synthesized by reaction of H2Pt(OH)6 with H[AuCl4] in a simple one-pot procedure in aqueous solution at pH 7 and comprises two equivalent PtIVO6(As(CH3)2)3 units which are… read more here.
Keywords: iii oxoanion; oxoanion ptiv2auiii3o6; platinum gold; ptiv2auiii3o6 ch3 ... See more keywords